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Applications of NMR Spectroscopy. Volume 2 by Atta-ur-Rahman, M. Iqbal Choudhary

By Atta-ur-Rahman, M. Iqbal Choudhary

Applications of NMR Spectroscopy, quantity 2, originally released by way of Bentham and now disbursed via Elsevier, provides the most recent advancements within the box of NMR spectroscopy, together with the research of plant polyphenols, the position of NMR spectroscopy in neuroradiology, NMR–based sensors, reports on protein and nucleic acid constitution and serve as, and mathematical formations for NMR spectroscopy in structural biology.

The totally illustrated chapters include accomplished references to the hot literature. The purposes awarded hide quite a lot of the sector, similar to drug improvement, clinical imaging and diagnostics, nutrition technological know-how, mining, petrochemical, technique keep watch over, fabrics technology, and chemical engineering, making this source a multi-disciplinary reference with huge applications.

The content material is perfect for readers who're looking experiences and updates, because it consolidates medical articles of a various nature right into a unmarried quantity. Sections are equipped in response to disciplines, similar to nutrition technology and scientific diagnostics. each one bankruptcy is written via eminent specialists within the field.

  • Consolidates the newest advancements in NMR spectroscopy right into a unmarried volume
  • Authored and edited by way of world-leading specialists in spectroscopy
  • Features entire references to the latest comparable literature
  • More than sixty five illustrations relief within the retention of key concepts

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Extra resources for Applications of NMR Spectroscopy. Volume 2

Sample text

Isoflavones In isoflavones the ring B is attached to position 3 of ring C (Fig. 21; structure 153). , Leguminosae, or bean) family of plant kingdom. There are about 900 naturally occurring isoflavones aglycones which have been further classified Applications of NMR Spectroscopy in Plant Polyphenols Application of NMR Spectroscopy, Vol. 2 51 into 14 classes and 23 subclasses based on the difference in their skeleton [253]. Some of the generally found isoflavones are given here (Fig. 21). 8 7 1 O 2 6 5 4 O HO 3 1' 2' HO O HO OH O 5' OH HO O HO OH Daidzein (156) O O OH OH O OH Genistin (155) O HO OH OH O OH Genistein (154) O O HO 3' 4' 6' 153 O O O O Daidzin (157) OH O OH Glycitein (158) Figure 21: Selected isoflavones.

Pro(antho)cyanidins The oligomers/polymers of catechins and epicatechins containing 2-7 monomeric units, are often referred to as proanthocyanidins. They are called proanthocyanidins because the acid-catalyzed cleavage of the polymeric chains produces anthocyanidins (Fig. 17). The structure variations among proanthocyanidins mainly depend on the interflavanic linkages and are sub classified as A-type and B-type proanthocyanidins. In A-type, the monomers are linked through C2-O-C5 or C2-O-C7 bonding, while in B-type the monomers are linked through C4-C6 or C4-C8.

2 37 Table 8: contd.... 6. Catechins and Epicatechins The isomers of flavanol at C-2 and C-3 if exist in trans configuration are called as catechin and if exist in cis configuration are called as epicatechin. , (+)-catechin (109), (−)-catechin (110), (+)-epicatechin (114) and (−)-epicatechin (115) (Fig. 16). The most abundantly occurring of the isomers in food plants are the (+)-catechin and (−)epicatechin (Fig. 16). These monomeric flavanols are found in many fruits but the skins of apples, grapes and blueberries are particularly rich of these compounds [195, 196].

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