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A New Principle of Equilibrium by Lewis G.N.

By Lewis G.N.

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Lebedeva, V. S. Pshezhetzkii, L. V. S. Enikolopyan, Dokl. Akad. Nauk SSSR 290, 1383 (1986) [I081 B. Pispisa, A. J. Schouten, G. Challa, J. Reedijk, J. Mol. Catal. S. S. F. W. Eustance, J. Am. Chem. 81, 6335 (1 959) [ l 1 I] A. S. Hay, P. Shenian, A. C. Gowan, P. F. Erhardt, W. R. Haaf, J. E. Theberge in Encycl. Polym. Sci. M. Bikales editor, Wiley, New York, 1969, Vol. 10, p. S. Hay, Polym. Eng. Sci. 16, 1 (1976) [113] E. Tsuchida, M. Kaneko, H. Nishide, Makromol. Chem. 151, 221 (1972) [114] E.

Polym. Sci. Polym. Chem. Ed. 15, 2059 ( I 977) [961 M. Sato, H. Shindo, K. Kondo, K. Takemoto, J. Polym. Sci. Polym. Chem. Ed. 18, 101 (1 980) [97] V. B. Sigitov, S. E. Kudaibergenov, E. A. Bekturov, Abstr. 7th All-Union Conf. on Catalytic Reactions in Liquid Phase, Alma-Ata 1988, p. 101 [98] H. Nishide, T. Minakota, E. Tsuchida, J. Mol. Catal. 15, 327 (1982) [99] H. Hirai, T. Furuta, J. Polym. Sci. Polym. Chem. Ed. 9, 459 (1971) [IOO] E. Bayer, W. Schumann, J. Chem. Chem. Commun. 12, 949 (1986) [I011 V.

This is inferred from the intramolecular cooperation of OOE blocks during complexing. Polyamides catalyze the interfacial nucleophilic substitution of hexyl bromide by 42 Chapter I: Catalytic Properties of Polymers in Solutions potassium acetate in CH3CN. The catalytic activity of polyamide increases with an increase in the chain length of an oligooxyethylene unit. The activity of polyamide does not actually depend on the type of acid components. The polymer effect in the reaction, as compared with the model compounds, increases with a decrease in the number of oxyethylene units in the amine component.

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